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- The Greenhouse Effect
- Harder greenhouse effect
- Greenhouse gases
- How large is the greenhouse?
- The vibrators
- The rotators
- Spectral transitions
- Greenhouse gas spectra
- Selective absorption
- Why is grass green?
- Planck emission
- Emission to space
- A MODTRAN Spectrum
- The hard bit
- Greenhouse gas concentrations
- Effects of greenhouse gases
- Emissions controversy
- Warming controversy
- Model predictions
- A simple model
- MODTRAN calculations
- A Sensitive Matter
- Greenhouse trace gases
- Is it the Sun?
- Sunspots
- An asymmetric world
- More asymmetry
- Carbon cycle
- Seasonal carbon cycle
- Isotope evidence
- The giver of life
- Origins of Fossil Fuels
- Burn the Fossil Fuel
- Seasonal changes
- More on Seasons
- Breaking News
- Books & Links
- King v Jack
- Biofuels; good or bad?
- Snowball Earth?
- Schwarzschild's Equation
- Scepticism
The concentrations of greenhouse gases in the atmosphere are very small compared to those of the main constituents, Nitrogen (78%) and Oxygen (21%), but nevertheless exert a significant effect on the temperature of the Earth's surface and its atmosphere
| Greenhouse gas | Concentration |
| Water vapour | 7600a ppmv |
| CO2 | 380 ppmv |
| N2O (nitrous oxide) | 320 ppbv |
| CH4 (methane) | 1780 ppbv |
| O3 (ozone) | 28b ppbv |
a This is the average concentration at sea level and varies considerably at that level. It also falls off with increasing altitude since it is not a 'permanent' gas like the other greenhouse gases
b This is the average concentration in the troposphere; the first ~15 km of the atmosphere. There is a higher concentration in the ozone layer in the stratosphere around 35 km altitude.
The units of concentration need some explanation. Those for water vapour and CO2 are parts per million by volume; ppmv. The other greenhouse gases have lower concentrations that are given as parts per billion by volume; ppbv.
By comparison the concentration of nitrogen [N2], 78% by volume is equivalent to 780,000 parts per million by volume.
Sometimes concentrations are given in terms of parts per million by mass (ppm) and are considerably different numbers from ppmv. This is because they take into account the relative molar masses of the gases. For example the 380 ppmv concentration of CO2 is 380 x 44/28.9 = 579 ppm. The relative molar mass of CO2 is 44 and the average value for the dry atmosphere is 28.9. Only chemists know about this!
The variation of CO2 concentration in the atmosphere from pre-industrial times is very important in assessing the possible enhancement of the greenhouse effect.
There are small concentrations of other gases in the atmosphere including the inert gases [He, Ne, Ar, Kr, and Xe] and carbon monoxide and hydrogen. And at even lower concentrations are lots of smelly things.