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- The Greenhouse Effect
- Harder greenhouse effect
- Greenhouse gases
- How large is the greenhouse?
- The vibrators
- The rotators
- Spectral transitions
- Greenhouse gas spectra
- Selective absorption
- Why is grass green?
- Planck emission
- Emission to space
- A MODTRAN Spectrum
- The hard bit
- Greenhouse gas concentrations
- Effects of greenhouse gases
- Emissions controversy
- Warming controversy
- Model predictions
- A simple model
- MODTRAN calculations
- A Sensitive Matter
- Greenhouse trace gases
- Is it the Sun?
- Sunspots
- An asymmetric world
- More asymmetry
- Carbon cycle
- Seasonal carbon cycle
- Isotope evidence
- The giver of life
- Origins of Fossil Fuels
- Burn the Fossil Fuel
- Seasonal changes
- More on Seasons
- Breaking News
- Books & Links
- King v Jack
- Biofuels; good or bad?
- Snowball Earth?
- Schwarzschild's Equation
- Scepticism
This is a description of the main greenhouse gases
Absorption of infrared radiation by the main components of the atmosphere, namely nitrogen and oxygen molecules, is forbidden by quantum laws. These indicate that m
olecules that are allowed to absorb and emit infrared radiation must either possess a permanent dipole moment—for example the bent water molecule in which the oxygen atom has a partially negative charge balanced by partially positive charges on the hydrogen atoms—or undergo vibrational motions that alter the dipole moment. An example of the latter is the linear CO2 molecule that has zero dipole moment because the partially negatively charged oxygen atoms are diametrically opposed, but when it undergoes a bending vibration the dipole moment is transiently non-zero. Thus water vapour and CO2 are greenhouse gases, as are to a lesser extent methane (CH4), nitrous oxide (dinitrogen oxide, N2O) and ozone (O3).